Chemical materials, usually monomers and oligomers, which
contain the grouping CH2=CHC-O-.
Adhesion:
The state in which two surfaces are held together by
interfacial forces which may consist of valence forces or
interlocking action or both.
Aromatic Ketone:
A group of chemical materials, most of which are sensitive
to light and readily form free radicals. The structure is ArCOR
(Ar). Some of these are useful as photoinitiators.
Catalyst:
Any material which aids in completion of a chemical reaction
without itself becoming part of the product.
Crosslinking Agent:
A reactive chemical which will form bonds between other
molecules in a formulation.
Cure:
Conversion of a material from a raw state to a finished and
useful condition by chemical reaction.
Dark Reaction:
Reactions which can take place in a closed container of
energy curable materials. Usually considered premature
polymerization.
Defocused System:
A curing system in which the substrate is positioned either
closer to or farther away than a focal distance.
Doped Lamps:
The specific wavelengths emitted from a UV lamp are
dependent upon the fill. Using mercury vapor is the norm. The
spectral output can be changed by adding dopants such as
beryllium or iron.
Dose:
Energy absorbed per unit mass. Usually listed in Megarads
(million rads).
Electron Beam:
A beam of charged electrons displaced from a metallic
filament by a high voltage source.
Epoxy Group:
A reactive part of a chemical molecule with the
structure
Extractables:
Any material which can be removed from a cured film by
solvents, usually measured as a weight difference.
Flash Xenon (Pulsed Xenon):
Lamp containing xenon gas which produces UV energy using a
special electrical transformer system.
Flexibility:
The ability of a material to twist, bend or otherwise
distort.
Focal Distance:
The distance from a lamps reflector at which peak energy can
be obtained.
Free Radical:
A reactive species having an unpaired electron which
initiates a reaction with a double bond. It is produced from its
stable paired state by energy absorption.
Gelation Point:
The point at which a liquid forms a semi-solid system.
Glass Transition Temperature:
The temperature at which a material changes from a soft,
rubbery state to a more brittle state.
Grind:
The dispersion of particles (usually pigments) in a coating
or ink.
Hardness:
The property of a material to resist indentation and
scratching.
Heat Cure (Thermal Cure):
A curing reaction which takes place when materials are
subjected to a form of heat.
Inert Atmosphere:
The blanketing (usually from air) with a nonreactive (inert)
gas, commonly nitrogen.
Megarad or Mrad:
One Mrad equals one million rads. The megarad is the term
used to describe the dose of radiation given.
Mercury Lamp:
Lamp in which light is generated through the presence of
mercury vapor. Most UV lamps are mercury vapor lamps.
Microwave:
Energy having wavelengths between 1 and 10 millimeters.
Monomer:
A molecule of relatively low molecular weight capable of
combining with itself or other similar molecules to form a
polymer.
Nanometer:
A unit of distance commonly used in measuring wavelengths in
the electromagnetic spectrum.
Oligomers:
A lower molecular weight resin or polymer which is used in a
energy curable formula.
Oxygen Inhibitor:
The effect of oxygen to terminate or retard the rate of
polymerization.
Ozone:
A form of oxygen that occurs when high energy electrical
discharge is present: O3.
Photoinitiator:
A molecule which when exposed to a specific wavelength of
energy forms a reactive species which starts the chain reaction
to cause polymer formation.
Photosensitizer:
A chemical which will transfer energy and form free radicals
by interacting with another chemical.
Plasticizer:
A compound added to increase flexibility and toughness of
the final product.
Polymerization:
A chemical reaction usually carried out with a catalyst,
heat or energy in which two or more reactively simple compounds
combine to form a macromolecule.
Post Cure:
Continuation of reactions of materials in the ink or
coating, after exposure to energy has ceased.
Reactive Diluent:
A chemical which serves two purposes in a formulation.
Thinning or viscosity reduction and providing reactivity with
other ingredients.
Shelf Life:
The amount of time a material may be stored under specified
conditions with no significant change in properties.
Stabilizers:
Additives to inks or coatings formulations which help to
extend shelf life, resistance to heat or other degradation.
Surface Slip:
The ability and ease of sliding of the surface of one
material over the surface of another.
Thixotropy:
A property of a liquid whereby its viscosity decreases upon
application of shear and increase when shear is removed.
Through Cure:
The curing of the bulk of a material down to and including
the material substrate interface as opposed to a surface cure
where only the material/air interface is cured.
Ultraviolet Light:
The light emitted in the 200 - 400 nanometer wavelength
range.
Ultraviolet Black Light:
Ultraviolet light built to operate at low power using a low
pressure lamp.
Window:
A metallic foil in an electron beam generating unit that
allows passage of energetic electrons from the beam.